This paper analyses the concept of "Positive Energy Leadership"(PEL) and the Structural Model of PEL from the systematic thinking. Based on the concept of PEL, this paper builds the Structural Model of PEL. The research results shows that PEL emphasizes on the leaders should excavation the positive energy from the environment, the individual leaders and the followers, and should transfer the positive energy in the process of the leadership. The content structure of PEL can be divided into three dimensions which are how the leaders deal with environment, the individual leaders and the followers with positive energy