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  DOI Prefix   10.20431


 

International Journal of Advanced Research in Chemical Science
Volume-4 Issue-1, 2017, Page No: 1-12
DOI: http://dx.doi.org/10.20431/2349-0403.0401001

Isotherm Analysis on the Removal of Ni (II) ION from Wastewater using APANC

S Arivoli1*, A Arasakumar2

PG and Research Department of Chemistry, Thiru Vi Ka Government Arts College, Thiruvarur, Tamilnadu, India.

Citation : S Arivoli, A Arasakumar, Isotherm Analysis on the Removal of Ni (II) ION from Wastewater using APANC International Journal of Advanced Research in Chemical Science. 2017;4(1):1-12.

Abstract


Nickel plays an important role in metallurgical, electroplating and other chemical industries. About 40% of the nickel produced is used in steel factories, nickel batteries and in the production of some alloys. On the other hand, it may pollute aqueous streams, arising therefore several environmental problems. An adsorbent prepared from Pandanus Amaryllifolius Stem Ash, by acid treatment was tested for its efficiency in removing nickel ion. The process parameters studied include agitation time, initial Nickel ion concentration, adsorbent dose, pH and temperature. The adsorption followed second order reaction equation and the rate is mainly controlled by intra-particle diffusion. The equilibrium adsorption data were correlated with Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Hurkins-Jura, Halsay, Radlich-Peterson, Jovanovic and BET isotherm models. The adsorption capacity (Qm) obtained from the Langmuir isotherm plot at an initial pH of 6.5 and at 30, 40, 50, 60 ± 0.5 0C. The influence of pH on metal ion removal was significant and the adsorption was increased with increase in temperature. A portion of the nickel ion was recovered from the spent APANC using 0.1M HC


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