International Journal of Advanced Research in Chemical Science
Volume-2 Issue-11, 2015, Page No:18-26
Bisamide and Tetrahydropyrimidine Sugar Surfactants Via Staudinger Reaction
Salih Mahdi Salman
Department of Chemistry-College of Medicine-University of Diyala
Citation : Salih Mahdi Salman, Bisamide and Tetrahydropyrimidine Sugar Surfactants Via Staudinger Reaction International Journal of Advanced Research in Chemical Science. 2015;2(11):18-26.
Abstract
The Staudinger reaction enables an easy access to sugar amide glycolipids including monoamide and bisamide at the anomeric positions by substitute the hydroxyl group after preparing the target hydroxyl group and protect the other hydroxyl groups. It’s possible to drive Staudinger reaction to cyclization reaction by control the solvent and the quantities of the reactants to produce tetrahydropyrimidine compounds instead of the double amide chains. This is considering as new methodology to synthesis tetrahydropyrimidine sugars. It is used to synthesis new sugar surfactants. Both bisamide and Tetrahydropyrimidine sugar are a new type of surfactants and are easily accessed as chemically pure compounds based from natural renewable resources e.g. sugar and fatty acids both are reasonable economic and environmental friendly.