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DOI Prefix 10.20431 |
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International Journal of Advanced Research in Chemical Science
Volume-2 Issue-10, 2015, Page No:22-25
Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-K2N2:N3)bis[(triisopropylphosphane)copper(I)]:an Efficient Catalyst for Interfacial Cycloaddition of Nitriles to Sodium Azide
Issam Kobrsi, Ghada Taisier Khader Alsaidi, Ahlam Mohammed Al-Shamsi
Department of Chemistry, The Petroleum Institute, Abu Dhabi, UAE
Citation : Issam Kobrsi, Ghada Taisier Khader Alsaidi, Ahlam Mohammed Al-Shamsi, Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-K2N2:N3)bis[(triisopropylphosphane)copper(I)]:an Efficient Catalyst for Interfacial Cycloaddition of Nitriles to Sodium Azide . 2015;2(10):22-25.
Abstract
Equimolar amounts of sodium azide dissolved in water were reacted with organic nitriles dissolved in an organic solvent and loaded with 10 mol% of the title complex. Efficient production of the tetrazolate anion was observed in the aqueous phase especially for nitriles that are insoluble in water.
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