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  DOI Prefix   10.20431


 

International Journal of Advanced Research in Physical Science
Volume 5, Issue 5, 2018, Page No: 17-23

Thermodynamic Description of the Cadmium-Nickel System

H. Azza1*, N. Selhaoui1, L. Bouirden1

1.Laboratory of Thermodynamics and Energy (L.T.E), Faculty of science, University IbnZohr, Agadir, Morocco.

Citation : H. Azza, N. Selhaoui, L. Bouirden, Thermodynamic Description of the Cadmium-Nickel System International Journal of Advanced Research in Physical Science 2018, 5(5) : 17-23

Abstract

The thermodynamic discription of the Cd-Ni binary system was carried out with the help of CAL culation of PHAse Diagram (CALPHAD) method. The solution phases (Liquid, HCP_A3 (Cd) and FCC_A1 (Ni)) were modeled with the Sublattice formalism and the excess term of the Gibbs energy with the RedlichKister equation. The intermetallic compounds Cd5Ni and CdNi which a narrow homogeneity range, were modeled using a two-sublattice model with a mutual substitution of Cd and Ni on both sublattices. The calculations based on the thermodynamic modeling are in good agreement with the phase diagram data and experimental thermodynamic values.


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