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DOI Prefix 10.20431 |
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Synthesis, and Spectral Studies of Demi-macrocycles of Ligand N2O2 with Ni (II) and Cu (II) Ions
Sameena Rasheed1*,Arvind Prasad Dwivedi2,M.U.Khan1
2.Department of chemistry, Govt. Sanjay Gandhi Smrati Auto., P.G., College Sidhi M.P India.
Citation : Synthesis, and Spectral Studies of Demi-macrocycles of Ligand N2O2 with Ni (II) and Cu (II) Ions International Journal of Advanced Research in Chemical Science 2018, 5(3) : 15-19
The new series of demi-macrocycles of the type [C14 H30 N2 O2 (Cl2 O4)2] having N2O2 as donors ligand were synthesized by the equimolar condensation reaction of ethane-1, 2-diamine in acetone in presenced of perchloric acid. The head unit of demi-macrocycle formed was proposed by the two acetone molecules [M (C14 H30 N2 O2) (ClO4)2] Where, M = Ni(II) and Cu(II) were formed by the reaction of proposed demi-macrocycle with respective metal salts. The complexes formed were characterized by the elemental analysis, conductance and magnetic susceptibilities measurements, and also by spectral methods.